First you need to decompress "toc" file from specific version you're using. You can do it with quickbms or offzip.exe
For example: offzip.exe -a toc outputfolder 0
After that, rename decompressed file to "toc" and replace it.
Then correct INI file for the folder where you have game data files
Then run some of these commands:
1. spiderman 99807473A3981A8D - will extract that asset
2. spiderman 99807473A3981A8D c:\spider\iw - will extract asset into folder with name you specified
3. spiderman list.txt - will extract ALL assets in list
asset lists (all assets, models only, maps only) for versions 1.00 & 1.05 - https://www60.zippyshare.com/v/3CUfzReQ/file.html
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